Paper-based Volatile Organic Compound Sensor using MultiWalled Carbon Nanotubes on a Polytetrafluoroethylene Membrane
Main Article Content
Abstract
In this research, a paper-based volatile organic compound (VOC) sensor using multiwalled carbon nanotubes (CNTs) on a polytetrafluoroethylene (PTFE) membrane was successfully fabricated. The optimum of CNT amount and the responses to VOC vapors were investigated. Firstly, CNTs were functionalized with oxygen-containing function groups by oxygen plasma for 30 min, followed by dispersing the functionalized CNTs in ethanol with a concentration of 0.01 mg/mL. Finally, the paper-based sensor was fabricated by vacuum filtration of CNT suspension. The amounts of CNTs on a membrane were controlled by the volume of the CNT suspension in the range of 20 – 40 mL. The film resistance decreased with a volume of CNT suspension. The CNT sensor formed from 30 mL of CNT suspension exhibited the optimum amount of CNT for VOC sensing. Moreover, the paper-based sensor shows the highest response to methanol and the lowest response to benzene. Such a different sensitivity is essentially due to the different polarities of VOC molecules. These results imply a potential use of CNT on a paper as a low-cost, flexible, portable and disposable VOC sensor.
Article Details
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
References
Kanan S, El-Kadri O, Abu-Yousef I, Kanan M. Semiconducting metal oxide based sensors for selective gas pollutant detection. Sensors 2009;9(10):8158-8196.
Fine GF, Cavanagh LM, Afonja A. Binions R. Metal oxide semi-conductor gas sensors in environmental monitoring. Sensors 2010;10(6):5469-5502.
Iijima S, Ichihashi T. Single-shell carbon nanotubes of 1-nm diameter. Nature 1993;363:
–605.
Winadda W, Shin-ichi H, Hirofumi K, Tomoaki M, Takashi I, Tatsuya I, Toru M, Kengo S, Hiroshi I, Kenjiro O, Mitsuhiro K. Single-walled carbon nanotube thin-film sensor for ultrasensitive gas detection. Jpn. J. Appl. Phys. 2005;44(2):L482.
Li J, Lu Y, Ye Q, Cinke M, Han J, Meyyappan M. Carbon nanotube sensors for gas and organic vapor detection. Nano Lett. 2003;3(7):929-933.
Qi P, Vermesh O, Grecu M, Javey A, Wang Q, Dai H, Peng S, Cho KJ. Toward large arrays of multiplex functionalized carbon nanotube sensors for highly sensitive and selective molecular detection. Nano Lett. 2003;3(3):347-351.
Muangrat W, Yordsri V, Maolanon R, Pratontep S, Porntheeraphat S, Wongwiriyapan
W. Hybrid gas sensor based on platinum nanoparticles/poly(methyl methacrylate)coated single-walled carbon nanotubes for dichloromethane detection with a high response magnitude. Diam. Relat. Mater. 2016;65:183-190.
Han JW, Kim B, Li J, Meyyappan M. Carbon nanotube based humidity sensor on cellulose paper. J. Phys. Chem. C. 2012;116(41):22094-22097.
Han JW, Kim B, Li J, Meyyappan M. A carbon nanotube based ammonia sensor on cellulose paper. RSC Adv. 2014;4:549-553.
Shobin LR, Manivannan S. Carbon nanotubes on paper: Flexible and disposable chemiresistors. Sens. Actuat. B Chem. 2015;220:1178-1185.
Jijun Z, Alper B, Jie H, Ping LJ. Gas molecule adsorption in carbon nanotubes and nanotube bundles. Nanotechnology 2002;13:195-200.
Kim T, Kwak D. Flexible voc sensors using conductive polymers and porous membranes for application to textiles. Fiber Polym. 2012;13(4):471-474.
Parikh K, Cattanach K, Rao R, Suh DS, Wu A, Manohar SK. Flexible vapour sensors using single walled carbon nanotubes. Sens. Actuat. B Chem. 2006;113:55-63.
Worawut W, Thanawee C, Rungroj M, Sirapat P, Supanit P, Winadda W. Poly(methyl methacrylate) and thiophene-coated single-walled carbon nanotubes for volatile organic compound discrimination. Jpn. J. Appl. Phys. 2016;55(2S):02BD04.
Chobsilp T, Muangrat W, Issro C, Chaiwat W, Eiad-ua A, Suttiponparnit K, Wongwiriyapan W, Charinpanitkul T. Sensitivity enhancement of benzene sensor using ethyl cellulose-coated surface-functionalized carbon nanotubes. J. Sensors. 2018;2018: 1-9.
Tripathi KM, Kim T, Losic D, Tung TT. Recent advances in engineered graphene and composites for detection of volatile organic compounds (VOCs) and non-invasive diseases diagnosis. Carbon. 2016;110:97-129.
Gupta O, Roy S, Mitra S. Enhanced membrane distillation of organic solvents from their aqueous mixtures using a carbon nanotube immobilized membrane. J. Membrane Sci. 2018;568:134-140.