Luminescent Behaviour of Monovalent Metals Nitrite/Nitrates Incorporated to Microcrystalline Cellulose Matrix by Sorption from Water Solutions

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Published: Dec 29, 2017
Keywords:
Microcrystal Cellulose Nitrite Nitrate Oxide Luminescence

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Serhii G. Nedilko
Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska str., 01601 Kyiv, Ukraine
Egor Reznichenko
Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska str., 01601 Kyiv, Ukraine;
Vasyl Sherbatskii
Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska str., 01601 Kyiv, Ukraine
Maxim Nedielko
Paton Electric Welding Institute of NASU, 11 Bozhenko Str., 03680 Kyiv, Ukraine

Abstract

The samples of the microcellulose matrix that contain particles of inorganic oxides, NaNO2, KNO2, CsNO3 and AgNO3, were made by sorption of these inorganic from the water solutions. Morphology of the concentration sets of such composite materials was studied with use of optical and electronic scanning microscope. The spectra and intensity of photoluminescence of the samples were studied too. It was found that oxides inclusions quench the luminescence of cellulose that can be used in principles for sensing these oxides in water solutions. Manifestation of the characteristics narrow zero-phonon lines in the luminescence of composites samples that contain inclusions of the sodium nitrite, NaNO2, allowed decreasing the limit of this oxide determination down to value 3.5x10-3 g/l.

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How to Cite
1.
Nedilko S, Reznichenko E, Sherbatskii V, Nedielko M. Luminescent Behaviour of Monovalent Metals Nitrite/Nitrates Incorporated to Microcrystalline Cellulose Matrix by Sorption from Water Solutions. Thai J. Nanosci. Nanotechnol. [Internet]. 2017 Dec. 29 [cited 2024 Nov. 24];2(2):31-42. Available from: https://ph05.tci-thaijo.org/index.php/TJNN/article/view/47
Issue
Vol. 2 No. 2 (2017): TJNN
Section
Research Articles
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References

! I. Siró and D. Plackett, Microfibrillated cellulose and new nanocomposite materials: a review, Cellulose 17 (2010) 459-494.

! S. Hokkanen, E. Repo, T. Suopajärvi, H. Liimatainen, J. Niinimaa and M. Sillanpää, Adsorption of Ni(II), Cu(II) and Cd(II) from aqueous solutions by amino modified nanostructured microfibrillated cellulose, Cellulose 21 (2014) 1471-1487.

! B. Pan, B. Pan, W. Zhang, L. Lv, Q. Zhang and S. Zheng, Development of polymeric and polymer-based hybrid adsorbents for pollutants removal from waters, Chemical Engineering Journal 151 (2009) 19-29.

! P. Kulpinski, M. Namyslak, T. Grzyb and S. Lis, Luminescent cellulose fibers activated by Eu3+ -doped nanoparticles, Cellulose 19 (2012) 1271-1278.

! P. Kulpinski, A. Erdman, T. Grzyb and S. Lis, Luminescent Cellulose Fibers Modified with Cerium Fluoride Doped with Terbium Particles, Polymer composites 37 (2016) 153-160.

! A. Erdman, P. Kulpinski and K. Olejnik, Application of nanocomposite cellulose fibers with luminescent properties to paper functionalization, Cellulose 23 (2016) 2087-2097.

! A. Erdman, T. Grzyb, P. Kulpinski, J. Lazarek, S. Lis, K. Olejnik, M. Reczulski, P.S. Szczepaniak and A. Wysocka-Robak, Estimation of fiber orientation in paper products by image analysis on-line system, Fibres & Textiles in Eastern Europe 2(116) (2016) 107-112.

! R. Atalla and S. Nagel, Laser-induced Fluorescence in Cellulose, Journal of the Chemical Society, Chemical Commuications 19 (1972) 1049-1050.

! R.P. Bateh and J.D. Winefordner, An evaluation of cellulose as a substrate for room-temperature phosphorescence, Talanta 29 (1982) 713-717.

! A. Castellan, H. Choudhury, R.S. Davidson and S. Grelier, Comparative study of stoneground wood pulp and native wood. 2. Comparison of the fluorescence of stone-ground wood pulp and native wood, Journal of Photochemistry and Photobiology A: Chemistry 81(2) (1994) 117–122.

! H. Tylli, I. Forsskåhl and C. Olkkonen, The effect of heat and IR radiation on the fluorescence of cellulose. Cellulose 7 (2000) 133-146.

! V. Pikulev, S. Loginova and V. Gurtov, Luminescence properties of silicon-cellulose nanocomposite. Nanoscale Research Letters, 7 (2012), 426-432.

! P. Korntner, T. Hosoya, T. Dietz, K. Eibinger, H. Reiter, M. Spitzbart, T. Röder, A.

Borgards, W. Kreiner, A.K. Mahler, H. Winter, Y. Groiss, A.D. French, U. Henniges,

A. Potthast and T. Rosenau, Chromophores in lignin-free cellulosic materials belong to three compound classes. Chromophores in cellulosics, XII. Cellulose 22(2) (2015) 10531062.

! Z. Zhou and Q. Wang, Two emissive cellulose hydrogels for detection of nitrite using terbium luminescence. Sensors and Actuators B 173 (2012) 833-838.

! S.G. Nedilko, S. Revo, M. Nedielko, T. Avramenko, K. Ivanenko and V. Scherbatskii, Luminescence of the Alkali-Metals Nitrites Incorporated into Cellulose. Matrix. Solid State Phenomena 230 (2015)147-151.

! S.G. Nedilko, S.L. Revo, V.P. Chornii, V.P. Scherbatskyi and M.S. Nedielko, Luminescent determination of nitrite traces in water solutions using cellulose as sorbent. Journal of Sensors and Sensor System 4 (2015) 31–36.

! M. Nedielko, S. Hamamda, O. Alekseev, V. Chornii, M. Dashevskii, M. Lazarenko, K. Kovalov, S.G. Nedilko, S. Tkachov, S. Revo and V. Scherbatskyi, Mechanical, Dielectric, and Spectroscopic Characteristics of “Micro/Nanocellulose + Oxide” Composites. Nanoscale Research Letters 17 (2017) 1862 - 1878.

! J.C. Fanning, The chemical reduction of nitrate in aqueous solution. Coordination Chemistry Reviews, 199 (2000) 159–179.

! I.K. Konstantinou, D.G. Hela and T.A. Albanis, The status of pesticide pollution insurface waters (rivers and lakes) of Greece. Part I. Review on occurrence and levels. Environmental Pollution 141 (2006) 555-570.

! Y.T. Kononenko, I.Ya. Kushnirenko, S.G. Nedilko and V.P. Sakun, Spectral trends and radiativeless transitions in solution and crystals of alkali – halide salts doped with molecular anions. (in Russian) Journal of Applied Spectroscopy 42 (1985) 85-89.

! M.U. Belii, I.Ya. Kushnirenko, S.G. Nedilko and V.P. Sakun, Spectral-luminescent properties of the luminescence centers in frozeen water solution of alkali-halide salts doped with NО2 -anions. Optics and Spectroscopy 58 (1985) 367-372.

! M.U. Belii, I.Ya. Kushnirenko, S.G. Nedilko and V.P. Sakun, Spectroscopic appearances of inter – ionic interactions in water solutions of alkali metals nitrites. (in Russian) Journal of Applied Spectroscopy 48 (1988) 835-839.

! P. Zugenmaier, Crystalline Cellulose and Derivatives: Characterization and Structures, Springer, Heidelberg, 2008.

! V.I. Kovalenko, Crystalline cellulose: structure and hydrogen bonds. Russian Chemical Reviews 79 (2010) 231-242.

! J.W. Sidman, Electronic and Vibrational States of the Nitrite Ion. I. Electronic States. Journal of the American Chemical Society 79 (1957) 2669-2674.

! M.H. Brooker and D.E. Irish, Raman and Infrared Spectral studies of solid alkali metal nitrites. Canadian Journal of Chemistry 49 (1971) 1289-1295.