วัสดุประสานตั้งต้นและอัตราส่วนผสมของจีโอพอลิเมอร์

Abideng Hawa; Krittiya  Ongwuttiwat

Authors

Abideng Hawa Infrastructure and Materials Innovation Research Unit, Department of Civil Engineering, Faculty of Engineering, Princess of Naradhiwas University, Amphoe Mueang Narathiwat, Narathiwat Province 96000
Krittiya Ongwuttiwat Infrastructure and Materials Innovation Research Unit, Department of Civil Engineering, Faculty of Engineering, Princess of Naradhiwas University, Amphoe Mueang Narathiwat, Narathiwat Province 96000

Keywords:

Geopolymer, Fly ash, Metakaolin, Slag, Palm oil ash

Abstract

The growth of demand for cement concrete around the world concerns the destruction of natural resources. Geopolymer materials show promise as a sustainable alternative to cement concrete. Pozzolan materials such as fly ash, metakaolin, slag, and palm oil ash have different chemical compositions. Various binder to alkaline, sodium silicate to sodium hydroxide, sand to the binder, and stone to binder mixed to geopolymer. Outstanding reviews papers undertaken to quantify and understand the effects of the variable mentioned for compressive strength in the literature. The review also provides insights into research gaps in this field to promote geopolymer research in the future.

References

G. Habert, J. B. D. de Lacaillerie, and N. Roussel, “An environmental evaluation of geopolymer based concrete production: reviewing current research trends,” Journal of Cleaner Production, vol. 19, no. 11, pp. 1229–1238, Jul. 2011.

J. X. Peng, L. Huang, Y. Zhao, P. Chen, L. Zeng, and W. Zheng, “Modeling of Carbon Dioxide Measurement on Cement Plants,” Advanced Materials Research, vol. 610–613, pp. 2120–2128, Dec. 2012.

C. Tam, M. Taylor, and D. Gielen, Energy efficiency and CO2 emissions from the global cement industry, 2006, IEA-WBCSD workshop.

Z. Zhang, J. L. Provis, A. Reid, and H. Wang, “Geopolymer foam concrete: an emerging material for sustainable construction,” Construction and Building Materials, vol. 56, pp. 113–127, April 2014.

J. Davidovits, (1994). “Global warming impact on the cement and aggregates industries,” World Resource Review, vol. 6, no. 2, pp. 263–278, July 1994.

A. Hawa, D. Tonnayopas, W. Prachasaree, and P. Taneerananon, (2013). “Development and performance evaluation of very high early strength geopolymer for rapid road repair,” Advances in Materials Science and Engineering, vol. 2013, 764180, August 2013.

A. Hawa, D. Tonnayopas, W. Prachasaree, and P. Taneerananon, “Investigation the effects of oil palm ash in metakaolin based geopolymer,” Ceramics-Silikaty, vol. 7, no. 4, pp. 319-327, 2013.

A. Mohajerani, D. Suter, T. Jeffrey-Bailey, T. Song, A. Arulrajah, S. Horpibulsuk, and D. Law, “Recycling waste materials in geopolymer concrete,” Clean Technologies and Environmental Policy, vol. 21, no. 3, pp. 493–515, January 2019.

J. Davidovits, “Geopolymers: inorganic polymeric new materials,” Journal Thermal Analysis, vol. 37, pp. 1633–1656, 1991.

M. Rabie, R. M. Irshidat, and N. Al-Nuaimi, “Ambient and heat-cured geopolymer composites: mix design optimization and life cycle assessment,” Sustainability, vol. 14, no. 9, pp. 1-17, April 2022.

A. Hawa, “Strength and microstructural of geopolymer mortar from palm oil ash containing aluminapowder with palm oil clinker aggregate,” Engineering and Applied Science Research, vol. 49, no. 6, pp. 731-743, October 2022.

M. S. Morsy, S. H. Alsayed, Y. Al-Salloum, and T. Almusallam, “Effect of sodium silicate to sodium hydroxide ratios on strength and microstructure of fly ash geopolymer binder,” Arabian Journal for Science and Engineering, vol. 39, pp. 4333-4339, April 2014.

F. N. Degirmenci, “Effect of sodium silicate to sodium hydroxide ratios on durability of geopolymer mortars containing natural and artificial pozzolans,” Ceramics-Silikáty, vol. 61, no. 4, pp. 340-350, 2017.

S. V. Patankar, Y. M. Ghugal, and S. S. Jamkar, “Effect of concentration of sodium hydroxide and degree of heat curing on fly ash-based geopolymer mortar,” Indian Journal of Materials Science, vol. 2014, 938789, May 2014.

A. Abdullah, K. Hussin, M. M. A. B. Abdullah, Z. Yahya, W. Sochacki, R. A. Razak, K. Bloch, and H. Fansuri, “The effects of various concentrations of NaOH on the inter-particle gelation of a fly ash geopolymer aggregate,” Materials, vol. 14, no. 5, 1111, February 2021.

ASTM C618-19, (2019). Standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete. ASTM International, West Conshohocken, PA.

S. V. Patankar, S. S. Jamkar, and Y. M. Ghugal, “Effect of fineness of fly ash on flow and compressive strength of geopolymer concrete,” Indian Concrete Journal, vol. 87, no. 4, pp. 57-61, April 2013.

อาบีเด็ง ฮาวา ปรีชา สะแลแม ซุลกีฟลี มามะ ซุลกิฟลี เดมะ และวรพจน์ ประสาเสรี, “สมบัติทางกลและโครงสร้างระดับจุลภาคของจีโอพอลิเมอร์เถ้าลอยที่ใช้เศษยางรถยนต์เป็นมวลรวมละเอียด” วารสารวิจัยและพัฒนา มจธ., ปีที่ 45, ฉบับที่ 1, หน้า 125-144, มกราคม-มีนาคม 2565.

A. Elimbi, H. K. Tchakoute, and D. Njopwouo, “Effects of calcination temperature of kaolinite clays on the properties of geopolymer cements,” Construction and Building Materials, vol. 25, no. 6, pp. 2805-2812, June 2011.

A. S. Albidah, “Effect of partial replacement of geopolymer binder materials on the fresh and mechanical properties: A review,” Ceramics International, vol. 47, no. 11, pp. 14923-14943, June 2021.

N. H. Jamil, M. M. A. B. Abdullah, F. C. Pa, H. Mohamad, W. M. A. W. Ibrahim, and J. Chairapa, “Influences of SiO2, Al2O3, CaO and MgO in phase transformation of sintered kaolin-ground granulated blast furnace slag geopolymer,” Journal of Materials Research and Technology, vol. 9, no. 6, pp. 14922-14932, November–December 2020.

E. Tiffo, J. B. B. Mbah, P. D. B. Belibi, J. N. Y. Djobo, and A. Elimbi, “Physical and mechanical properties of unheated and heated kaolin based-geopolymers with partial replacement of aluminium hydroxide,” Materials Chemistry and Physics, vol. 239, 122103, January 2020.

G. Liang, H. Zhu, H. Li, and H. Guo, “Comparative study on the effects of rice husk ash and silica fume on the freezing resistance of metakaolin - based geopolymer,” Construction and Building Materials, vol. 293, 123486, July 2021.

O. A. Mayhoub, E. A. R. Nasr, Y. Ali, and M. Kohail, “Properties of slag based geopolymer reactive powder concrete,” Ain Shams Engineering Journal, vol. 12, no. 1, pp. 99-105, March 2021.

M. Zerzouri, S. Alehyen, R. Hamzaoui, L. Ziyani, and A. Loukili, “Durability of Moroccan fly ash-based geopolymer binder,” Materials Letters, vol. 304, 13673, December 2021.

O. Shee-Ween, H. Cheng-Yong, L. Yun-Ming, M. M. A. B. Abdullah, H. L. Ngee, L. W. L. Chan, O. Wan-En, N. A. Jaya, and N. Yong-Sing, “Cold-pressed fly ash geopolymers: effect of formulation on mechanical and morphologi- cal characteristics,” Journal of Materials Research and Technology, vol. 15, pp. 3028-3046, November–December 2021.

P. Payakaniti, N. Chuewangkam, R. Yensano, S. Pinitsoontorn, and P. Chindaprasirt, “Changes in compressive strength, microstructure and magnetic properties of a high-calcium fly ash geopolymer subjected to high temperatures,” Construction and Building Materials, vol. 265, 120650, December 2020.

X. Jiang, Y. Zhang, R. Xiao, P. Polaczyk, M. Zhang, W. Hu, Y. Bai, and B. Huang, “A comparative study on geopolymers synthesized by different classes of fly ash after exposure to elevated temperatures,” Journal of Cleaner Production, vol. 270, 122500, October 2020.

P. Qian,L.Y. S. Wang, Y. Alrefaei, and J. G. Dai, “Experimental study on full-volume fly ash geopolymer mortars: Sintered fly ash versus sand as fine aggregates,” Journal of Cleaner Production, vol. 263, 121445, August 2020.

P. Nuaklong, A. Wongsa, V. Sata, K. Boonserm, J. Sanjayan, and P. Chindaprasirt, “Properties of high-calcium and low-calcium fly ash combination geopolymer mortar containing recycled aggregate,” Heliyon, vol. 5, no. 9, e02513, September 2019.

S. K. Shill, S. Al-Deen, M. Ashraf, and W. Hutchison, “Resistance of fly ash based geopolymer mortar to both chemicals and high thermal cycles simultaneously,” Construction and Building Materials, vol. 239, 117886, April 2020.

P. Chindaprasirt and U. Rattanasak, “Characterization of the high-calcium fly ash geopolymer mortar with hot-weather curing systems for sustainable application,” Advanced Powder Technology, vol. 28, no. 9, pp. 2317-2324, September 2017.

S. C. Moghaddam, R. Madandoust, M. Jamshidi, and I. M. Nikbin, “Mechanical properties of fly ash-based geopolymer concrete with crumb rubber and steel fiber under ambient and sulfuric acid conditions,” Construction and Building Materials, vol. 281, 122571, April 2021.

A. Wongkvanklom, P. Posi, A. Kampala, T. Kaewngao, and P. Chidaprasirt, “Beneficial utilization of recycled asphaltic concrete aggregate in high calcium fly ash geopolymer concrete,” Case Studies in Construction Materials, vol. 15, e00615, December 2021.

M. T. Ghafoor, Q. S. Khan, A. U. Qazi, M. N. Sheikh, and M. N. S. Hadi, “Influence of alkaline activators on the mechanical properties of fly ash based geopolymer concrete cured at ambient temperature,” Construction and Building Materials, vol. 273, 121752, March 2021.

P. Chindaprasirt and W. Chalee, “Effect of sodium hydroxide concentration on chloride penetration and steel corrosion of fly ash-based geopolymer concrete under marine site,” Construction and Building Materials, vol. 63, pp. 303-310, July 2014.

P. K. Sarker, S. Kelly, and Z. Yao, “Effect of fire exposure on cracking, spalling and residual strength of fly ash geopolymer concrete,” Materials & Design, vol. 63, pp. 584-592, November 2014.

I. P. Segura, P. A. Jensen, A. J. Damo, N. Ranjbar, L. S. Jensen, and M. Canut, “Influence of sodium‑based activators and water content on the fresh and hardened properties of metakaolin geopolymers,” SN Applied Sciences, vol. 4, 283, September 2022.

M. S. Saif, M. O. P. El-Hariri, A. I. Sarie-Eldin, B. A. Tayeh, and M. F. Farag, “Impact of Ca+ content and curing condition on durability performance of metakaolin-based geopolymer mortars,” Case Studies in Construction and Materials, vol. 16, e00922, June 2022.

H. Tanyildizi, M. Ziada, M. Uysal, N. D. Güngor, and A. Coskun, “Comparison of bacteria-based self-healing methods in metakaolin geopolymer mortars,” Case Studies in Construction Materials, vol. 16, e00895, June 2022.

A. Hawa, D. Tonnayopas, and W. Prachasaree, “Performance evaluation and microstructure characterization of metakaolin-based geopolymer containing oil palm ash,” Scientific World Journal, vol. 2013, 857586, October 2013.

M. S. Eisa, E. A. Fahmy, and M. E. Basiouny, “Using metakaolin-based geopolymer concrete in concrete pavement slabs,” Innovative Infrastructure Solutions, vol. 7, no. 1, October 2021.

M. S. Eisa, M. E. Basiouny, and E. A. Fahmy, “Drying shrinkage and thermal expansion of metakaolin-based geopolymer concrete pavement reinforced with biaxial geogrid,” Case Studies in Construction Materials, vol. 17, e01415, December 2022.

A. Albidah, A. Alsaif, A. Abadel, H. Abbas, and Y. Al-Salloum, “Role of recycled vehicle tires quantity and size on the properties of metakaolin-based geopolymer rubberized concrete,” Journal of Materials Research and Technology, vol. 18, pp. 2593-2607, May–June 2022.

A. Albidah, A. Altheeb, F. Alrshoudi, A. Abadel, H. Abbas, and Y. Al-Salloum, “Bond performance of GFRP and steel rebars embedded in metakaolin based geopolymer concrete,” Structures, vol. 27, pp. 1582-1593, October 2020.

A. B. Moradikhou, A. Esparham, and M. J. Avanaki, “Physical & mechanical properties of fiber reinforced metakaolin-based geopolymer concrete,” Construction and Building Materials, vol. 251, 118965, August 2020.

R. Abbas, M. A. Khereby, H. Y. Ghorab, and N. Elkhoshkhany, “Preparation of geopolymer concrete using Egyptian kaolin clay and the study of its environmental effects and economic cost,” Clean Technologies and Environmental Policy, vol. 22, pp. 669-687, January 2020.

F. N. Al-Husseinawi, W. Atherton, Z. Al-Khafaji, M. Sadique, and M. Z. Yaseen, “The Impact of molar proportion of sodium hydroxide and water amount on the compressive strength of slag/Metakaolin (Waste Materials) geopolymer Mortar,” Advances in Civil Engineering, vol. 2022, 5910701, October 2022.

Z. Ou, R. Feng, T. Mao, and N. Li, “Influence of mixture design parameters on the static and dynamic compressive properties of slag-based geopolymer concrete,” Journal of Building Engineering, vol. 53, 104564, August 2022.

S. Oyebisi, F. Olutoge, P. Kathirvel, I. Oyaotuderekumor, D. Lawanson, J. Nwani, A. Ede, and R. Kaze, “Sustainability assessment of geopolymer concrete synthesized by slag and corncob ash,” Case Studies in Construction Materials, vol. 17, e01665, December 2022.

M. A. Salih, A. A. A. Ali, and N. Farzadnia, “Characterization of mechanical and microstructural properties of palm oil fuel ash geopolymer cement paste,” Construction and Building Materials, vol. 65, pp. 592-603, August 2014.

N. Ranjbar, M. Mehrali, U. J. Alengaram, H. Simon, H. S. C. Metselaar, and M. Z. Jumaat, “Compressive strength and microstruc- tural analysis of fly ash/palm oil fuel ash based geopolymer mortar under elevated temperatures,” Construction and Building Materials, vol. 65, pp. 144-121, August 2014.

B. A. Salami, Z. A. Johari, and M. Maslehuddin, “Impact of added water and superplasticizer on early compressive strength of selected mixtures of palm oil fuel ash-based engineered geopolymer composites,” Construction and Building Materials, vol. 109, pp. 198-206, April 2016.

P. Nuaklong, A. Wongsa, V. Sata, K. Boonserm, J. Sanjayan, and P. Chindaprasirt, “Properties of high-calcium and low-calcium fly ash combination geopolymer mortar containing recycled aggregate,” Heliyon, vol. 5, e02513, September 2019.

S. S. Jamkar, Y. M. Ghugal, and S. V. Patankar, “Effect of fly ash fineness on workability and compressive strength of geopolymer concrete,” Indian Concrete Journal, vol. 87, no. 4, pp. 57-62, April 2013.

A. Noushini and A. Castel, “The effect of heat-curing on transport properties of low-calcium fly ash-based geopolymer concrete,” Construction and Building Materials, vol. 112, pp. 464-477, June 2016.

P. Sajan, T. Jiang, C. Lau, G. Tan, and Ng Kan, “Combined effect of curing temperature, curing period and alkaline concentration on the mechanical properties of fly ash-based geopolymer,” Cleaner Materials, vol. 1, 100002, December 2021.

Z. Zuhua, Y. Xiao, Z. Huajun, and C. Yue, “Role of water in the synthesis of calcined kaolin-based geopolymer,” Applied Clay Science, vol. 43, no. 2, pp. 218-223, February 2009.

M. R. Wang, D. C. Jia, P. G. He, and Y. Zhou, “Influence of calcination temperature of kaolin on the structure and properties of final geopolymer,” Materials Letters, vol. 64, no. 22, pp. 2551-2554, November 2010.

S. Oyebisi, F. Olutoge, P. Kathirvel, I. Oyaotuderekumor, D. Lawanson, J. Nwani, A. Edi, and R. Kaze, “Sustainability assessment of geopolymer concrete synthesized by slag and corncob ash,” Case Studies in Construction Materials, vol. 17, e01665, December 2022.

A. Kumar and R. Kumar, “Mechanical activation of fly ash: Effect on reaction, structure and properties of resulting geopolymer,” Ceramics International, vol. 37, pp. 533–541, March 2011.

M. Hojati and A Radlin, “Shrinkage and strength development of alkali-activated fly ash-slag binary cements,” Construction and Building Materials, vol. 150, pp. 808–816, September 2017.

S. J. Chithambaram, S. Kumar, and M. M. Prasad, “Thermo-mechanical characteristics of geopolymer mortar,” Construction and Building Materials, vol. 213, pp. 100–108, July 2019.

P. Nath, and P. K. Sarker, “Effect of GGBFS on setting, workability and early strength properties of fly ash geopolymer concrete cured in ambient condition,” Construction and Building Materials, vol. 66, pp. 163–171, September 2014.

N. Ismail and H. El-hassan, “Development and characterization of fly ash – slag blended geopolymer mortar and lightweight concrete,” Journal of Materials in Civil Engineering, vol. 30, no. 4, pp. 1–14, January 2018.

Y. Ling, K. Wang, W. Li, G. Shi, and P. Lu, “Effect of slag on the mechanical properties and bond strength of fly ash-based engineered geopolymer composites,” Composite Part B Engineering, vol. 164, pp. 747–757, May 2019.

A. Hawa, D. Tonnayopas, and W. Prachasaree, “Effect of water-to-powder ratios on the compressive strength and microstructure of metakaolin based geopolymers,” Indian Journal of Engineering and Materials Sciences, vol. 24, pp. 499-506, December 2017.

Binder Materials and Mix Proportion of Geopolymer

Authors

Keywords:

Abstract

References

Downloads

Published

How to Cite

Issue

Section

License

Information

Language

Current Issue